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Organic Chemistry

Carbon and its chains: hydrocarbons, functional groups, naming, isomerism and organic reactions.

Summary

Organic chemistry studies carbon compounds. Carbon forms four bonds and can join to itself in long chains, branches or rings, with single, double or triple bonds. Hydrocarbons contain only C and H: alkanes (-ane, single bonds, CₙH₂ₙ₊₂), alkenes (-ene, one double bond), alkynes (-yne, triple) and aromatics such as benzene. Names are built from a prefix for the number of carbons (meth-, eth-, prop-, but-, pent-…) and an ending for the family.

Functional groups give each family its properties: alcohols (–OH, -ol), aldehydes (–CHO, -al), ketones (C=O in the middle, -one), carboxylic acids (–COOH), esters (which smell fruity) and amines (–NH₂). Compounds with the same formula and different structure are isomers. The typical reactions are combustion (CO₂ + H₂O), addition to double bonds, esterification and polymerisation, which gives plastics such as polythene.

Key points

  • Carbon forms 4 bonds and chains.
  • Hydrocarbons: only C and H.
  • Alkanes -ane, alkenes -ene, alkynes -yne.
  • Prefixes: meth-, eth-, prop-, but-, pent-…
  • Alcohol –OH, aldehyde –CHO, ketone C=O, acid –COOH.
  • Acid + alcohol → ester + water.
  • Isomers: same formula, different structure.
  • Combustion: CO₂ + H₂O; addition at double bonds.

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